3.8 Article

exo-Glycals from glycosyl cyanides. First generation of C-glycosylmethylene carbenes from 2,5-and 2,6-anhydroaldose tosylhydrazones

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b102963k

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In a one-pot reaction acylated glycosyl cyanides were transformed with Raney nickel-sodium hypophosphite into 2,5- and 2,6-anhydroaldose tosylhydrazones, which gave exo-glycals under Bamford-Stevens conditions.

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