Journal
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Volume -, Issue 3, Pages 296-301Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b008748n
Keywords
-
Categories
Ask authors/readers for more resources
The acid hydrolytic cleavage of 1 to 2, assisted by a neighbouring benzamide group, was kinetically investigated in a wide range of HCl concentrations (1.67-8.7 M) and at various temperatures. Kinetic measurements were performed also in the presence of LiCl at constant ionic strength (I = 5 M). The rate determining step of the acid hydrolysis of 1 was recognized through the investigation of the acid catalyzed cyclization of 3 to 2. Thermodynamic activation parameters were calculated and the experimental data discussed. The participation of the neighbouring benzamide group was evaluated to be about 7.3 x 10(3).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available