Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 170, Issue -, Pages 211-220Publisher
GORDON BREACH PUBLISHING, TAYLOR & FRANCIS GROUP
DOI: 10.1080/10426500108040599
Keywords
deoxygenation; thioethers; reductive coupling; sulfoxides; sulfonyl chlorides; disulfides
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Molybdenum pentachloride (MoCl5) in the presence of NaI in dry acetonitrile or zinc powder in anhydrous THF converts sulfoxides to their thioethers in high yields. Sulfonyl chlorides can be readily reduced to their corresponding disulfides with MoCl5/NaI/MeCN at room temperature or with MoCI5/Zn/MeCN under reflux conditions in high yields.
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