Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 176, Issue -, Pages 165-171Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500108055114
Keywords
acylals; dithiane; dithiolane; geminal diacetate; oxathiolane; silica chloride
Categories
Ask authors/readers for more resources
Acylals react with 1,3-propanedithiol, 1,2-ethanedithiol and 2-mercaptoethanol in the presence of silica chloride to give 1,3dithianes, 1,3-dithiolanes and 1,3-oxathiolanes in excellent yields in CH2Cl2 at room temperature. It has been observed that acylals were more reactive than their aldehydes but less reactive than acetals and ketals. Also aliphatic acylals survive under these conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
