4.7 Article Proceedings Paper

Isothermal Photo Differential Scanning Calorimetry - Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 65, Issue 2, Pages 435-443

Publisher

SPRINGER
DOI: 10.1023/A:1012424918321

Keywords

photo-DSC; photoinitiating systems; photopolymerization

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The effect of photoinitating (camphorquinone/amines) system concentration and sample thickness on the photopolymerization of triethyleneglycol dimethacrylate/2-hydroxypropyl methacrylate has been investigated. The rate of photopolymerization reaches a maximum and then decreases as the concentration of photoinitiating system increases. This effect has been intepreted as inner filter effect.

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