Journal
NEW JOURNAL OF CHEMISTRY
Volume 25, Issue 11, Pages 1365-1367Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b106545a
Keywords
-
Categories
Ask authors/readers for more resources
An aluminium phenylphosphonate, has Al(OH)(O3PC6H5), been studied. Its poor long-range crystallographic organisation required the use of local probe techniques such as P-31 and Al-27 MAS NMR and XAS. An unexpectedly narrow and symmetric Al-27 MAS NMR signal was obtained, with an isotropic chemical shift that has not been observed earlier in aluminium phosphonates. XANES and EXAFS studies showed unambiguously that this signal had to be attributed to a five-fold coordination site, the first observed for a phosphonato-aluminum atom.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available