Journal
POLYMER DEGRADATION AND STABILITY
Volume 74, Issue 2, Pages 263-270Publisher
ELSEVIER SCI LTD
DOI: 10.1016/S0141-3910(01)00156-2
Keywords
enzymatic degradation; aliphatic copolyesters; poly(butylene succinate); poly(butylene adipate); poly(butylene succinate-co-butylene adipate)s; lipase
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A series of high molecular weight polyesters, poly(butylene succinate-co-butylene adipate)s was prepared from dimethyl succinate, dimethyl adipate and 1,4-butanediol by catalyzed transesterification in the melt. The structure, average molecular weights and physical properties of the resulting random aliphatic copolyesters were characterized by H-1 NMR, solution viscosity, gel permeation chromatography, differential scanning calorimetry and X-ray analysis. The effect of copolymer composition on the physical and thermal properties, as well as enzymatic degradation was investigated. The enzymatic degradation was performed in a buffer solution with Candida cylindracea lipase at 30 degreesC. The highest enzymatic degradation rate was observed for the copolyester containing 50 mol.% butylene succinate units (PBAS-50). This copolyester has the lowest crystallinity and these results suggest that degree of crystallinity has a strong influence on the enzymatic degradation rate. (C) 2001 Elsevier Science Ltd. All rights reserved.
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