4.4 Article Proceedings Paper

Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC)

Journal

JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume 31, Issue 7, Pages 799-809

Publisher

KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1017587310150

Keywords

alcohol oxidation; direct alcohol fuel cell; electrode material; reaction mechanism

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The electrooxidation of some low molecular weight alcohols, such as ethanol, ethylene glycol and n-propanol, is discussed in terms of reaction mechanisms and catalytic activity of the anode material. Some examples of a single cell, using a proton exchange membrane (PEM) as electrolyte, are given to illustrate interesting results, particularly for the direct electrooxidation of ethanol. This alcohol may replace methanol in a direct alcohol fuel cell.

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