The synthesis and characterization of N-(diphenylthiophosphinyl)-P-phenyl-thiophosphonamidic acid phenyl ester and related compounds chiral at phosphorus

The synthesis and spectroscopic characterization of three novel phosphorus(V) compounds, chiral at phosphorus, are reported. All three compounds were characterized by X-ray crystallography, and for one compound a H-1-P-31 HETCOR experiment was performed. (C) 2001 Elsevier Science B.V. All rights reserved.