Journal
COORDINATION CHEMISTRY REVIEWS
Volume 211, Issue -, Pages 235-254Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00275-7
Keywords
group VI compounds; cyclopentadienyl carbonyl compounds; photochemistry
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The structure, bonding, and photochemistry of the Group VI cyclopentadienyl metal carbonyl compounds of the general form (eta (5)-C5H5)(2)M-2(CO)(6), where M = Cr, Mo, and W, and their ring-substituted and ring-coupled derivatives is critically reviewed. The emphasis of this review is to bring together evidence for reaction intermediates and mechanisms to assist in the interpretation of the chemistry of these materials and to guide future investigations. (C) 2001 Elsevier Science B.V. All rights reserved.
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