Journal
TOPICS IN CATALYSIS
Volume 16, Issue 1-4, Pages 49-56Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1023/A:1016622612521
Keywords
oxygen storage; oxygen mobility; TWC; OBD; isotopic exchange
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Oxygen storage capacity (OSC) of TW catalysts has a strong impact on their performances under oscillatory conditions. This paper reviews the different methods developed for OSC measurements, the effects of catalyst composition on OSC as well as the impact of OSC on TW catalysis, concentrating on the results obtained in our laboratory. Use of OSC measurements for catalysts control (on-board diagnostic) is also examined. The role of superoxide species as intermediates in the oxygen storage process will be emphasized. Finally, we shall review the recent developments on CeZr-based oxides.
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