Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 55, Issue 6-7, Pages 381-398Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH02098
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Catalytic chain transfer polymerization is a very efficient and versatile free-radical polymerization technique for the synthesis of functional macromonomers. The process is based on the ability of certain transition metal complexes, most notably of low-spin Co-II complexes such as cobaloximes, to catalyse the chain transfer to monomer reaction. A brief overview is given of the applications and the mechanistic understanding of catalytic chain transfer polymerization.
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