Journal
CHIMIA
Volume 56, Issue 12, Pages 721-723Publisher
SWISS CHEMICAL SOC
DOI: 10.2533/000942902777679920
Keywords
chemical modification; directed evolution; enzymes; hybrid catalysts; transition metal catalysis
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The first step in applying the recently proposed concept concerning the application of directed evolution to the creation of selective hybrid catalysts is described, specifically the covalent attachment of Mn-salen moieties and of Cu-, Pd-, and Rh-complexes of dipyridine derivatives as well as the implantation of a diphosphine moiety in a protein, future steps being cycles of mutagenesis/screening.
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