Journal
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
Volume A39, Issue 11, Pages 1361-1368Publisher
MARCEL DEKKER INC
DOI: 10.1081/MA-120015736
Keywords
aerobic oxidation; polymer-bound Schiff base ternary complexes; linear aliphatic olefins; epoxidation
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The polymer-bound Schiff base ternary cobalt complexes (PS-SalPhe-Co-L (L = Phen, Bipy and 8HQ)) have been prepared from the polymer bound Schiff base ligand, cobalt salt and the second ligand, such as 1,10-phenanthroline(phen), 2,2',-bipyridyl(bipy) and 8-quinolinol(8HQ). The polymer-bound Schiff base ternary cobalt complexes were characterized by the infrared spectra and ICP-AES. The catalytic activity of the complexes has been studied in aerobic epoxidation of long-chain linear aliphatic olefins. It showed that 1-octene or 1-decene can be directly oxidized by molecular oxygen catalyzed by PS-SalPhe-Co-L (L = Phen, Bipy and 8HQ), which afford the 1,2-epoxy alkane.
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