Journal
CERAMICS INTERNATIONAL
Volume 40, Issue 9, Pages 13869-13872Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2014.05.105
Keywords
Powders: solid state reaction; X-ray methods; Electrical properties; Oxide superconductors
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The effect of Cr substitution on the formation of Tl-1223 type phase is reported. Samples with nominal starting composition (Tl1-xCrx) Ba2Ca2Cu3O9 (Tl-1223) for x=0.3-0.9 were prepared using the solid state reaction method. The samples were studied by powder X-ray diffraction method, electrical resistance versus temperature measurements and scanning electron microscopy (SEM). The x=0.3, 0.4 and 0.5 samples showed a mixed Tl-1223 and Tl-1223 phase. The samples with x=0.6, 0.7 and 0.8 showed a single Tl-1223 phase. The x=0.6 sample showed the highest onset temperature of 124 K and zero-resistance temperature of 116 K. Our results showed that the (Tl,Cr)-1223 phase can be stabilized with Cr substitutions without the use of Sr. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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