3.8 Article Proceedings Paper

Instrumented falling weight impact of coinjection-molded multipolypropylene sandwich plaques containing beta-phase polypropylene core

Journal

JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS
Volume B41, Issue 4-6, Pages 881-889

Publisher

MARCEL DEKKER INC
DOI: 10.1081/MB-120013071

Keywords

coinjection-molding; instrumented falling weight impact; isotactic polypropylene; skin-core morphology; alpha-phase polypropylene; beta-phase polypropylene

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The instrumented falling weight perforation impact behavior of coinjection-molded multipolypropylene sandwich plaques of various compositions having a beta-phase isotactic polypropylene (PP) homopolymer core was studied at room temperature and T = -40degreesC, respectively. The results were compared with those achieved on injection-molded monomaterial plaques of alpha- and beta-polymorphs. It was found that the coinjection strategy is beneficial only if the skin-forming alpha-phase PP has a markedly lower molecular weight than the beta-nucleated core PP. Sandwich plaques with PP copolymer skins exhibited an outstanding per-foration impact resistance. The coinjection strategy for extrusion grade PPs yielded no improvement. Perforation impact at T = -40degreesC showed a prominent toughness reduction of the multi polypropylene plaques which became comparable with that of the monolayer plaques.

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