Broad band down conversion from ultra violet light to near infrared emission in YVO4:Bi3+, Yb3+ as spectral conversion phosphor for c-Si solar cells

Vanadate based down conversion phosphors have been synthesized by a novel co-precipitation technique. The effect of pH on crystal structure, particle size, morphology and luminescence properties were investigated by XRD, SEM-EDAX, FT-IR and PL measurements. As different from other reports (blue, green emission) the produced phosphors have shown greenish yellow emission, owing to their fine particle size. A broad band excitation (280-370 nm), ascribed to S-1(0)-> P-3(1) and an intense greenish yellow band emission (410-700 nm) attributed to P-3(1) -> S-1(0) transition of Bi3+ were observed. A strong greenish-yellow emission was measured with 3 mol. % of Bi3+ ions, as an optimum dopant concentration. The characteristic NIR emission of Yb3+, owing to F-2(5/2)-> F-2(7/2) was recorded at 1039 nm, as a result of efficient energy transfer from Bi3+ to Yb3+, ions. The phosphors with chemical composition as Y0.96VO4: Bi-0.03(3+), Yb-0.01(3+) and Y0.87VO4: Bi-0.03(3+), Yb-0.1(3+) are suggested to be the novel candidates for the efficient down conversion of broad band ultra violet (UV) light into visible/near infrared (NIR) emission, as DC layers on c-Si solar cells for better harvesting the solar spectrum via spectral matching phenomena. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.