4.4 Article

Dirhodium (II) carboxylate-catalysed oxidation of allylic and benzylic alcohols

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 1, Pages 139-141

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)02048-2

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Allylic and benzylic alcohols are oxidised to the corresponding carbonyl compounds using tert-butyl hydroperoxide. preferably in stoichiometric amounts, and dirhodium(II) tetraacetate as catalyst (1 mol%) in dichloromethane at ambient temperature. (C) 2001 Elsevier Science Ltd. All rights reserved.

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