Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 6, Pages 652-653Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b110793c
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Treatment of an amido-ytterbium complex with n-BuLi leads to the isolation and structural characterization of a mixed amido-imido-ytterbium or imido-ytterbium complex, respectively, depending upon the molar ratios of the reactants; the Yb-N distance and the linearity of the imido N atom strongly suggest the presence of a formal Yb=N multiple bond in these novel complexes.
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