4.7 Article

Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 5, Pages 480-481

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b109827f

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Novel monodentate phosphorus ligands containing the 1,1 spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).

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