Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 13, Pages 1368-1369Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b204319j
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Free-radical polymerization of methyl methacrylate and styrene using conventional organic initiators in the room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([ C(4)mim][PF6]) is rapid and produces polymers with molecular weights up to 10x higher than from benzene; both polymerization and isolation of products were achieved without using VOCs, offering economic as well as environmental advantages.
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