4.7 Article

Catalytic insertion of diazo compounds into N-H bonds: the copper alternative

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 24, Pages 2998-2999

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b207389g

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The complexes Tp(X)Cu (Tp(X) = homoscorpionate) catalyse the insertion of diazo compounds into nitrogen-hydrogen bonds of amines and amides, under very mild conditions, with quantitative yields being obtained with equimolar ratios of reactants.

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