Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 8, Pages 846-847Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b201221a
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The synthesis of 4-(C6H4-p-NBu2)-2,2:6,2-terpyridine and the strongly enhanced second-order NLO response of its Zn(II), Ru(III) and Ir(III) complexes are reported, evidencing for the first time a shift from positive to negative value of the ligand quadratic hyperpolarizability by varying the nature of the metal centre.
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