Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 766-767Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b111687h
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The highly enantiomerically enriched silyllithium compound lithiomethylphenyl(1-piperidinylmethyl) silane (4) reacts stereospecifically with chlorosilanes, but over a period of several hours slow racemization in solution at room temperature occurs, which can be supressed by a transmetalation reaction with MgBr2(thf)(4).
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