Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 149, Issue 3, Pages A307-A318Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1447224
Keywords
-
Ask authors/readers for more resources
The validity of estimating the solid phase diffusion coefficient, D-s, of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy (EIS) method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating D-s. The influence of parameters such as the exchange current density, radius of active material particle, solid phase conductivity, porosity, volume fraction of inert material, and thickness of the porous carbon intercalation electrode, the solution phase diffusion coefficient, and transference number, on the validity of D-s estimation, is evaluated. A simple dimensionless group is developed to correlate all the results. It shows that the accurate estimation of D-s requires large particle size, small electrode thickness, large solution diffusion coefficient, and low active material loading. Finally, a full model'' method is developed for the cases where the modified EIS method does not work well. (C) 2002 The Electrochemical Society.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available