3.8 Article

Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b108336h

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Reaction of a salicylaldiminato ligand with M(CH2-SiMe2Ph)(3)(THF)(2) (M = Sc, Y) leads to diastereoselective formation of highly thermally stable L2MR complexes whose reactivity with dihydrogen to form Group 3 metal hydrides is described.

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