Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 4, Issue 8, Pages 1386-1392Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b108686c
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As a simple example of an autonomous motor, the characteristic patterns in the self-motion of a camphoric acid boat depending on the chemical environment were investigated at the air/aqueous interface. The uniform motion of a camphoric acid boat changed to intermittent motion and its period increased depending on the concentration of phosphate ions. The nature of the self-motion changed reversibly with the addition of chemical stimuli to the air/aqueous interface. The camphoric acid layer adsorbed on a mica surface was observed by atomic force microscopy (AFM) to investigate how the microscopic state of the camphoric acid layer varied with pH. The nature of the self-motion was reproduced by a numerical calculation in relation to the surface tension, which depends on the surface concentration of the camphoric acid layer.
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