3.8 Article

Synthesis and catalytic activity of three-coordinate zinc cations

Journal

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume -, Issue 22, Pages 4071-4073

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b208165m

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Reaction between DADZnR(2) and either B(C6F5)(3) or ZnR2 and [DADH][B(C6F5)(4)] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and epsilon-caprolactone [DAD = (MeC =NC6H3Pr2i-2,6)(2)].

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