Incorporation of coal combustion residuals into calcium sulfoaluminate-belite cement clinkers

In recent years, calcium sulfoaluminate-belite (CSAB) cement has been promoted as a sustainable alternative to Portland cement due to lower energy used and less CO2 emitted during production, while providing comparable performance. However, a potential problem facing the widespread adoption and production of CSAB cement is the cost and availability of raw materials and it is therefore desirable to find alternative raw materials to keep costs competitive. In this study, two CSAB cement clinkers with a similar target phase composition were synthesized from combinations of natural and waste materials (coal combustion residuals). The two CSAB cement clinkers were compared against a CSAB clinker made from reagent-grade chemicals, enabling examination of the effects of impurities on performance. Cements made from the clinkers were examined for hydration rate, hydration product formation, dimensional stability, and compressive strength. (C) 2012 Elsevier Ltd. All rights reserved.