Journal
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Volume -, Issue 4, Pages 555-560Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b107066p
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Condensation of 1,1'-diaminoferrocene with a range of salicylaldehydes resulted in the formation of the corresponding salen-type ligands in high yields. The ability of these compounds to serve as ligands was demonstrated by the formation of several 1 : 1 Zr and Ti complexes, one of which was structurally characterized and was found to feature a (t-Bu)Salfen(2-) ligand in a square-planar conformation. In addition, a related Schiff-base ligand was synthesized by condensing diaminoferrocene with 2,4-petanedione and a Zr complex of this ligand was isolated.
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