Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 4, Issue 15, Pages 3578-3582Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b202625m
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Two-color REMPI and ZEKE photoelectron spectra are presented for the trans-acetanilide Ar complex. Methyl rotor features are prominent in the cluster spectra and appear with unperturbed frequencies and intensities compared to acetanilide, indicating that the argon atom exerts little influence on the methyl rotor from its van der Waals binding position above the aromatic ring. Analysis of the spectra allowed the determination of the S-1 and D-0 barrier heights ( 50 and 320 cm(-1)), and the S-0 and S-1 0a-1e splitting (3.9 and 2.0 cm(-1)).
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