Journal
CELLULOSE
Volume 20, Issue 1, Pages 339-353Publisher
SPRINGER
DOI: 10.1007/s10570-012-9819-9
Keywords
Polysaccharide; Carbonate; Carbamate; Aminolysis; NMR spectroscopy
Funding
- German Science Foundation (DFG) [HE 2054/11-1]
- Thuringian Ministry for Education, Science and Culture [B514-09051, NanoConSens]
Ask authors/readers for more resources
Well soluble dextran-, cellulose-, starch-, and pullulan aryl carbonates were synthesized applying p-NO2-phenyl chloroformate, phenyl chloroformate, and phenyl fluoroformate. Aminolysis of the products obtained, using aliphatic amines or benzyl amines, yield novel soluble polysaccharide carbamates. The influence of the reaction conditions on the reaction efficiency depending on polysaccharide, reagent, and reaction parameters including temperature was studied. Thus a synthesis strategy was developed for the easy and efficient design of structures of polysaccharide-based materials. The products were characterized by means of NMR-, UV-Vis- and FTIR spectroscopy, elemental analysis, and size exclusion chromatography.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available