Journal
CELLULOSE
Volume 21, Issue 1, Pages 535-540Publisher
SPRINGER
DOI: 10.1007/s10570-013-0095-0
Keywords
Chitin; Nanofiber; Hydrogel; Mercerization; Tensile properties
Funding
- Grants-in-Aid for Scientific Research [23780185] Funding Source: KAKEN
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Cellulose and chitin exist in nature as highly crystalline nanofibers. Previously, we reported preparing unique hydrogels from cellulose nanofibers by a simple NaOH treatment without use of any specific solvents or cross-linking agents. In the present study, a similar gel preparation was applied to beta-chitin nanofibers extracted from purified squid pen powder. The crystal structure of chitin nanofibers was transformed from beta-chitin to alpha-chitin by NaOH(aq) treatment above 30 wt%. The crystal conversion involving the interdigitation among adjacent nanofibers caused the formation of stable hydrogels with a alpha-chitin nanofiber network. The use of ethanol voided the dissolution during neutralization and enabled preparation of a higher crystalline hydrogel with high mechanical strength. It achieved a Young's modulus of 16.6 MPa, a tensile strength of 7 MPa and a strain at break of 52.2 %, on average. Finally, we note that the shrinkage of the cellulose I and beta-chitin nanofibers in aqueous NaOH solutions was caused by the release of tensile residual stress due to the intracrystalline swelling in NaOH solutions.
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