Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 12, Issue 7, Pages 1978-1992Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b203007a
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This article highlights the progress made in the design, synthesis and study of supramolecular fullerene architectures that are based upon biomimetic organization principles. In particular, an overview of hydrogen-bonding, pi-pi stacking, metal-mediated complexation and electrostatic motifs is given, which have been used to incorporate fullerenes into well-ordered arrays. Owing to the presence of fullerenes, as an integrative building block, the majority of the presented molecular assemblies exhibit unique and remarkable features. Issues relevant to electron-donor-electron-acceptor interactions are considered.
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