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Free radical reaction of sodium arenesulfinates with acetylenes: New regio- and stereoselective preparation of (E)-beta-(phenylseleno)vinyl sulfones

SYNTHETIC COMMUNICATIONS (2002)

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Journal

SYNTHETIC COMMUNICATIONS
Volume 32, Issue 8, Pages 1243-1249

Publisher

MARCEL DEKKER INC
DOI: 10.1081/SCC-120003616

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Categories

Chemistry, Organic

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Free radical reaction of terminal acetylenes with sodium arenesulfinates and diphenyl diselenide in aqueous acetic acid afforded high yields of the regio- and stereoselective (E)-beta-(phenylseleno) vinyl sulfones.

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