Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 178, Issue -, Pages 214-218Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2015.08.008
Keywords
Trifluoromethylation; Photocatalysis; Radical reaction; 1,2-Carbon migration
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Funding
- Soonchunhyang University Research Fund
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2014006224]
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A visible-light-induced photoredox trifluoromethylation/1,2-carbon migration sequence of alkenols is described. This approach provides a mild and operationally simple access to the synthesis of CF3-substituted cyclic ketones via trifluoromethylation and 1,2-carbon migration of 1-(1-arylvinyl)cyclobutanol derivatives. (C) 2015 Elsevier B.V. All rights reserved.
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