Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 169, Issue -, Pages 38-49Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2014.11.001
Keywords
Functionalization of gem difluoromethyl; group Carbon-carbon bond formation; Base promoted addition reaction
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Funding
- Department of Science and Technology, New Delhi
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From gem-difluoromethyl group of 1,1,2,2-tetrafluoroethyl ether and 2,2-difluoroalkylamide, proton can be removed by potassium bis(trimethylsilyl)amide in DMF, THF or toluene. The generated nucleophiles are then condensed with benzophenones, benzaldehydes or Schiffs bases to provide new fluorinated alcohols and amines. Some interesting solvent effects are also observed., (C) 2014 Elsevier B.V. All rights reserved.
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