Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 67, Issue 1, Pages 113-118Publisher
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1013789931016
Keywords
DTA; intercalation; montmorillonite; organoclay; XRD
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The comparison of thermal stabilities of different organoclay intercalation complexes is presented in this work. Montmorillonite/monomer and montmorillonite/polymer intercalation complexes with similar basal spacings show a pronounced difference in changes of d(001) values after 30 min heating. The hydrophilic and/or organophilic surface modification of the starting montmorillonite is an important factor affecting the intercalated amount of organic material and thus the expansion of the sheet silicate structure.
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