Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 179, Issue -, Pages 188-192Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2015.08.003
Keywords
Fluoroaliphatics; Phenonium rearrangement; Deoxofluorination reactions; Fluorocyclohexanes; All-cis tetrafluorocyclohexane motif
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Funding
- Engineering and Physical Sciences Research Council [EP/K039210/1, EP/K022946/1, 1518001, EP/H022651/1, EP/F03055X/1, EP/K031252/1] Funding Source: researchfish
- EPSRC [EP/K022946/1, EP/K031252/1, EP/F03055X/1, EP/K039210/1, EP/H022651/1] Funding Source: UKRI
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A study focused on the synthesis of a derivative of all-cis phenyl-2,3,5,6-tetrafluorocyclohexane, incorporating a methyl group at the benzylic position, found that the fluorination reactions of diepoxide and diol precursors, were susceptible to rearrangement and unexpected products. The origin of these rearranged products can be rationalised by aryl migrations occurring via phenonium ion intermediates, in adventitious pathways occurring during deoxofluorination reactions with hydrogen fluoride reagents. (C) 2015 Elsevier B.V. All rights reserved.
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