Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 179, Issue -, Pages 106-115Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2015.06.008
Keywords
Catalyst; Fluoroalkenes; Packing; Palladium; Polycyclic aromatic hydrocarbons; Semiconductors
Categories
Funding
- JSPS KAKENHI [25288016, 2562015]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [15K05414, 26105705, 25288016] Funding Source: KAKEN
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Treatment with a cationic palladium(II) catalyst promoted the Friedel-Crafts-type cyclization of 1,1-difluoro-1-alkenes bearing a biphenyl skeleton to afford regioselectively fluorinated (pinpoint-fluorinated) phenanthrenes via C-F bond activation. The obtained pinpoint-fluorinated phenanthrenes were observed to be organized by pi-pi and C-H center dot center dot center dot F interactions to exhibit columnar and layer structures in the solid state. (C) 2015 Elsevier B.V. All rights reserved.
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