Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 4, Issue 3, Pages 227-230Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(02)00256-4
Keywords
nanoparticles; conducting polymer; ITIES; facilitated ion transfer; liquid-liquid
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This communication reports the production of polyphenylpyrrole coated silver nanoparticles at the liquid/liquid interface by an EC-type mechanism. In the electrochemical step of the reaction N-phenylpyrrole facilitates the transfer of the silver ion from an aqueous to an organic phase. This step is followed by a slow homogeneous electron transfer reaction from the N-phenylpyrrole to the silver ion followed by polymerization and metal cluster growth. (C) 2002 Elsevier Science B.V. All rights reserved.
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