Journal
JOURNAL OF FLUORESCENCE
Volume 26, Issue 1, Pages 1-9Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10895-015-1713-z
Keywords
Fluorescent chemosensor; Copper ion-selective; Fluorescein-N-methylimidazole electron transfer
Funding
- Center of Research Excellence in Nanotechnology (CENT) in King Fahd University of Petroleum and Minerals
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A new highly selective, chromogenic, and fluorogenic Cu2+ chemosensor, fluorescein-N-methylimidazole conjugate 1, and another fluorescein-N-imidazole conjugate 2 were synthesized and investigated by UV-visible and fluorescence spectroscopy. The sensing of Cu2+ quenches the emission band of 1 at lambda(max) = 525 nm, with an association constant (K (a) = 1.0 x 10(7) M-1) and a stoichiometry of 1:1 in a buffered H2O: MeOH solution (4:1, pH = 7.4). The Cu2+ detection limit for chemosensor 1 is 37 nM. The presence of the N-methyl group in 1 increased the Cu2+ binding selectivity, resulting in a stronger binding constant and a broader pH working range (pH 5-10) in comparison to 2. The fluorescence in 1 and 2 is caused by electron transfer phenomenon from the imidazole nitrogen to fluorescein, which is readily inhibited by Cu2+ binding.
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