Synthesis, characterization and crosslinking of functional star-shaped poly(epsilon-caprolactone)

Star-shaped low molecular weight poly(epsilon-caprolactone)s (PCLs) were synthesized and functionalized with crosslinkable terminal groups for subsequent crosslinking. The epsilon-caprolactone (CL) prepolymers were polymerized by ring-opening in the presence of polyglycerine (PGL) as an initiator (1, 3, and 5mol%) and Sn(II)2-ethylhexanoate as a catalyst. Characterization of the prepolymer by C-13/H-1 nuclear magnetic resonance (NAIR) spectroscopy, size exclusion chromatography (SEC), differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR) revealed a six-armed star-shaped structure for the prepolymer with the molecular weight controlled by the ratio of PGL and CL. Functionalization of the hydroxyl-terminated prepolymer was carried out with maleic. or itaconic anhydride. In both cases, the characterization of the functionalized prepolymer showed that the hydroxyl groups were completely substituted. The functionalized PCLs were successfully crosslinked through the reaction of double bonds. The crosslinking was induced either thermally with organic peroxide or photochemically with a photosensitive initiator. Characterization of the crosslinked PCLs by Soxhlet extraction, DSC and FTIR showed that the itaconic double bond was much more reactive in thermal crosslinking than the maleic double bond.. Thus, the crosslinked prepolymers that were functionalized with itaconic double bonds achieved a gel content of about 90%. A gel content of 100% was achieved with several compositions where crosslinking agents were employed.. (C) 2002 Society of Chemical Industry.