Journal
GREEN CHEMISTRY
Volume 4, Issue 5, Pages 424-425Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b207096k
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Carbon dioxide was used not only as a reaction medium but also as a reagent to activate ArCl in the palladium-catalyzed Ullmann-type coupling. In liquid carbon dioxide not only various aromatic iodides and bromides but also aromatic chlorides, non-reactivated substrates in earlier reports, were coupled in moderate to good yields in the presence of Pd/C, zinc and H2O at room temperature overnight.
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