4.3 Article

Synthesis and crystal structure of a cadmium complex with isonicotinate

Journal

JOURNAL OF COORDINATION CHEMISTRY
Volume 55, Issue 1, Pages 123-127

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970211875

Keywords

isonicotinate; cadmium(II); crystal structure

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The cadmium(II) complex, [Cd(iso)(2)(H2O)(4)](where iso is the anion of isonicotinic acid), has been synthesized and characterized by element analysis, thermal analysis and IR spectroscopy. An X-ray crystal structure reveals that the cadmium ion is trans-octahedral with two pyridyl nitrogens and two aqua oxygens in equational positions and two aqua oxygens in axial positions. The complex forms a three-dimensional network through intermolecular hydrogen bonds.

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