Journal
REACTION KINETICS AND CATALYSIS LETTERS
Volume 79, Issue 1, Pages 101-109Publisher
SPRINGER
DOI: 10.1023/A:1024163818818
Keywords
enantioselective; hydrogenation; chiral modifier; isophorone
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Asymmetric heterogeneous catalytic hydrogenation of isophorone has been investigated over (S)-alpha,alpha-diphenyl-2-pyrrolidinemethanol modified Pd. The influence of solvent and support effects is discussed. The impact of water, acidic and basic additives on enantioselectivity is described.
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