Synthesis and crystal structure of [Nd(H2O)(2)](2)(C2O4)(3)

Some crystals of [Nd(H2O)(2)](2)(C2O4)(3) were synthesized hydrothermally by heating at 200degreesC for 8 days an aqueous suspension of neodymium oxalate decahydrate in presence of terephthallic acid and guanidinium carbonate. They crystallize in the orthorhombic system, space group P2(1)2(1)2(1), with a = 8.6702(7) Angstrom, b = 9.558(2) Angstrom, and c = 17.009(2) Angstrom. The structure of this complex is built up by two independent neodymium atoms, three bischelating oxalate ligands, and four water molecules forming a rectangle building unit of 6-membered ring, [Ln(H2O)(2)(C2O4)](6). The packing of these units leads to a layer parallel to the plane (001). However, the neodymium atoms of two neighbor layers share an edge of oxalato oxygen atoms thus giving a double- layer. The three dimensionality between these double- layers is insured by hydrogen bonds of water molecules which are bound to the neodymium atoms. There is no zeolitic water molecule. The two neodymium atoms are nine-coordinated. In both cases, the coordination polyhedron can be described as a distorted tricapped trigonal prism.