Journal
CANADIAN JOURNAL OF CHEMISTRY
Volume 81, Issue 11, Pages 1223-1227Publisher
CANADIAN SCIENCE PUBLISHING
DOI: 10.1139/V03-121
Keywords
hydrosilylation; catalysis; silaheterocycles; silyl cations
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A metal-free catalytic intramolecular hydrosilylation reaction is reported. The key intermediates in the catalytic cycle are silyl cationic species. The reaction is used to produce 2-silanorbornanes 2 from 3-cyclopentenemethylsilanes 1 under mild conditions and in high isolated yields.
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