Journal
KINETICS AND CATALYSIS
Volume 44, Issue 1, Pages 129-134Publisher
PLEIADES PUBLISHING INC
DOI: 10.1023/A:1022537121514
Keywords
-
Categories
Ask authors/readers for more resources
The particle morphology and surface structure of nickel metal in metal-filamentous carbon catalysts were found to depend on the nature of coke-forming species used in the synthesis of catalysts. Metal carbonization with hydrocarbons that are characterized by high thermodynamic stability results in the formation of well-cut metal particles the surface of which is formed by (110) facets. Selective hydrogenation reactions of diene and acetylene hydrocarbons to olefins are typical of these catalysts. In the catalytic decomposition of hydrocarbons with relatively low thermodynamic stability, metal particles become irregular in shape, and their surface is formed by (111) facets. In this case, the reactions of full hydrogenation of olefin, diene, and acetylene hydrocarbons to corresponding alkanes take place. These data are consistent with the found dependence of the catalytic properties of catalysts on the character of the exterior faceting of active metal particles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available