4.7 Article

Self-assembly of an unpolar enantiomerically pure helicate-type metalla-cryptand

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 20, Pages 2526-2527

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b309026d

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Chiral tetraketone ligands are obtained by Claisen-type condensation of 4-bromoacetophenone with the acetone ketal of L-tartraic acid diethylester and lead with gallium( III) or iron( III) ions in self-assembly processes to dinuclear helicate-type cryptands which are able to bind lithium cations.

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